FUNGICIDES

摘要

These are proposed new propene acid formations and their stereoisomers characteristic of fungicide activity. The formula (I) of the same is:where K is an oxygen and sulphur atom; Z is unchanged or changed aril or changed or unchanged heteroaryl; X is O, S(O)n, NR<4>, CR<1>R<2>, CHR<5>, CO, CR<1>(OR<2>), C= CR<1>R<2>, CHR<1>CHR<2>, CR<1>=CR<2>, CHR<1>CR<2>=CH, C=C, OCHR<1>, CHR<1>O, OCHR<1>O, S(O)nCHR<1>, S(O)nCHR<1>O, CHR<1>S(O)n, CHR<1>OSO2, NR<4>CHR<1>, CHR<1>NR<4>, CO2, O2C, SO2O, OSO2, CO, CO.CO, COCHR<1>, COCHR<1>O, CHR<1>CO, CHOH.CHR<1>, CHR<1>.CHOH,CONR<4>, OCONR<4>, NR<4>CO, CSNR<4>, OCS.NR<4>, SCO.NR<4>, NR<4>CO2, NR<4>CS, NR<4>CSO, NR<4>COS, NR<4>CONR<4>, S(O)nNR<4>, NR<4>S(O)n, CS2, S2C, CO.S, SCO, N=N, N=CR<1>, CR<1>=N, CHR<1>CHR<2>CH(OH), CHR<1>OCO, CHR<1>SCO, CHR<1>NR<4>CO, CHR<1>NR<4>COR<4>, CHR<1>CHR<2>CO, O.N=CR<1>, CHR<1>O.N=CR<2>, CO.OCR<1>R<2>, CHR<1>CHR<2>CHR<3>, OCHR<1>CHR<2>, (CH)mO, CHR<1>OCHR<2>, CHR<1>CHR<2>O, OCHR<1>CHR<2>O, S(O)nCHR<1>CHR<2>, CHR<1>S(O)nCHR<2>, CHR<1>CH<2>S(O)n, CR<1>=NNR<4>, NR<4>N=CR<1>, CHR<1>CONR<2>, CHR<1>OCO.NR<2>, CH=CHCH2O, COCHR<1>CHR<2>O or (R<5>)2P<+>CHR<2>Q; A, B and E may be the same of different and is H, halogen atom, oxy-group, C1-4 alkyl, C1-4 alkoxy group, C1-4 halogen alkyl, C1-4 halogen alkyl-group, C1-4 alkyl carbonyl, C1-4 alkoxycarbonyl, phenoxy-, nitro- or cyanic-group; R<1>, R<2> or R<3> may be the same or different and are H, C1-4 alkyl or phenyl; R<4> is H, C1-4 alkyl or COR<1>; R<5> is unchanged or changed phenyl; Q is halogen anion; n is 0, 1 or 2, and m is 3, 4 or 5 under the condition if Z is unchanged phenyl and X and K is oxygen atom, A, B and E at the same time can not be a hydrogen atom.