发明名称 Process for producing methionine
摘要 A process for producing methionine, while corrosion of a pipe and a reaction vessel is well inhibited, is provided including the following steps (1) to (3), wherein a content of thiols in 3 -methylthiopropanal is 500 ppm or less, based on the propanal, and a content of hydrogen sulfide in 3-methylthiopropanal is 60 ppm or less, based on the propanal; step (1) in which 3 -methylthiopropanal is reacted with hydrogen cyanide in the presence of a base to give 2 -hydroxy -4-methylthiobutanenitrile; step (2) in which the 2-hydroxy-4-methylthiobutanenitrile obtained in step (1) is reacted with ammonium carbonate to give 5-(&bgr;-methylmercaptoethyl) hydantoin; and step (3) in which the 5-(&bgr;-methylmercaptoethyl)hydantoin obtained in step (2) is hydrolyzed in the presence of a basic potassium compound to give methionine.
申请公布号 US8119837(B2) 申请公布日期 2012.02.21
申请号 US20090613580 申请日期 2009.11.06
申请人 AZEMI TAKUSHI;KOIZUMI YOSHIYUKI;SUMITOMO CHEMICAL COMPANY, LIMITED 发明人 AZEMI TAKUSHI;KOIZUMI YOSHIYUKI
分类号 C07C323/22 主分类号 C07C323/22
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