发明名称 Method for preventing polymerization of (meth)acrylic acid and esters thereof and method for the production thereof
摘要 This method of preventing polymerization of methacrylic acid inn the process of its production is characterized by comprising using, in a refining column, a combination of N-nitrosophenylhydroxylamine or salt thereof with an N-oxyl compound, an N-hydroxy-,2,2,6,6-tetramethylpiperidine compound and a 2,2,6,6-tetramethylpiperidine compound. In this method, N-nitrosophenylhydroxylamine or a salt thereof rises inside a refining column under splitting part thereof to effectively inhibit polymerization of (meth)acrylic acid or the like. The above polymerization in both vapor and liquid phases can be inhibited more effectively by the combined use of the compounds mentioned above.
申请公布号 US6599397(B2) 申请公布日期 2003.07.29
申请号 US20010875541 申请日期 2001.06.06
申请人 NIPPON SHOKUBAI CO., LTD. 发明人 SAKAMOTO KAZUHIKO;NAKAE TOMOHIRO;OKOCHI KAZUO;UEMURA MASAHIRO;NAKAHARA SEI
分类号 C07C51/50;C08F2/38;(IPC1-7):B01D3/00;B01D59/00 主分类号 C07C51/50
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